Table of Contents
Key Concepts
Carbon and its Compounds
The element of life and infinite combinations
Catenation: The ability of carbon to form long chains, branches, and rings with other carbon atoms.
Tetravalency: Having a valency of 4, it can bond with 4 other atoms simultaneously.
Diamond: 3D rigid structure, hardest substance, insulator.
Graphite: Hexagonal layers that slide, soft/lubricating, excellent conductor of electricity.
Fullerene (C-60): Football-shaped spherical molecule.
Alkanes (Saturated): Single bonds only. General formula $\mathrm{C_nH_{2n+2}}$.
Alkenes (Unsaturated): At least one double bond. Formula $\mathrm{C_nH_{2n}}$.
Alkynes (Unsaturated): At least one triple bond. Formula $\mathrm{C_nH_{2n-2}}$.
Alcohol: $\mathrm{-OH}$ (Suffix: -ol)
Aldehyde: $\mathrm{-CHO}$ (Suffix: -al)
Ketone: $\mathrm{>C=O}$ (Suffix: -one)
Carboxylic Acid: $\mathrm{-COOH}$ (Suffix: -oic acid)
Addition: Unsaturated hydrocarbons add hydrogen (Hydrogenation) in the presence of Ni/Pd catalysts to become saturated.
Substitution: In presence of sunlight, Chlorine replaces Hydrogen in alkanes.
Ethanoic Acid ($\mathrm{CH_3COOH}$): Also called acetic acid (vinegar). Weak acid, reacts with carbonates to give $\mathrm{CO_2}$ gas.
Concept Deep Dive
Why Graphite Conducts but Diamond Doesn’t
A tale of valence electronsIn Diamond, each carbon atom is bonded to 4 other carbon atoms. All 4 of its valence electrons are locked up in tight covalent bonds. There are zero free electrons, making it a perfect insulator.
In Graphite, each carbon atom is bonded to only 3 other carbon atoms in flat, hexagonal sheets. This leaves exactly one free, delocalized electron per carbon atom. These free electrons can move through the sheets, allowing graphite to conduct electricity exceptionally well!
The Cleaning Action of Soap
How Micelles trap dirtWhen soap is added, the hydrophobic tail (carbon chain) attaches itself to the oily dirt, because it hates water. The hydrophilic head (ionic part) faces outward, bonding with the surrounding water. These soap molecules surround the oil droplet entirely, creating a microscopic sphere called a Micelle.
Because the outside of the micelle is covered in negative charges, the micelles repel each other and stay suspended in the water as an emulsion. When you rinse with water, the whole micelle (carrying the dirt inside) washes away!
Compare & Contrast
✗ Soaps
- Sodium or Potassium salts of long-chain carboxylic acids.
- Biodegradable and environmentally friendly.
- Fail in Hard Water: React with Calcium and Magnesium ions in hard water to form an insoluble white solid called scum, wasting the soap.
✓ Detergents
- Sodium salts of long-chain sulphonic acids or ammonium salts.
- Often non-biodegradable (can cause water pollution).
- Work in Hard Water: Their calcium/magnesium salts are soluble in water, so they do NOT form scum and lather easily even in hard water.
Common Mistakes to Avoid
Propanol ($\mathrm{CH_3-CH_2-CH_2OH}$) is an Alcohol.
Propanal ($\mathrm{CH_3-CH_2-CHO}$) is an Aldehyde.
Writing an ‘a’ instead of an ‘o’ changes the entire chemical family and will cost you marks.
Exam Tips
Cheat Sheet:
– X = Ethanol (Alcohol reacts with Na).
– Y = Ethanoic Acid.
– Z = Ester (sweet smelling).
Expected Exam Questions
Board Pattern Questions
Class 10 · Science · CBSE ExamCarbon and its compounds (hydrocarbons) undergo highly exothermic combustion reactions. They release a tremendous amount of heat and light energy when burned in air. Furthermore, saturated hydrocarbons burn with a clean flame without leaving much residue (soot), making them excellent, efficient fuels.
Equation: $\mathrm{CH_{4(g)} + 2O_{2(g)} \rightarrow CO_{2(g)} + 2H_2O_{(g)} + Heat + Light}$
A homologous series is a family of organic compounds having the same general formula, the same functional group, and similar chemical properties.
Characteristics:
1. Any two consecutive members differ in their formula by a $\mathrm{-CH_2}$ unit, and in their molecular mass by $14 \text{ u}$.
2. All members show similar chemical properties (because they have the same functional group).
3. They show a gradual change (gradation) in their physical properties (like melting/boiling points) as molecular mass increases.
Vegetable oils contain unsaturated carbon chains (double bonds). When hydrogen gas is passed through vegetable oils in the presence of a catalyst like Nickel ($\mathrm{Ni}$) or Palladium ($\mathrm{Pd}$), an Addition Reaction occurs. The double bonds break, hydrogen atoms are added, and the oil converts into saturated solid fats (vegetable ghee). This process is called Hydrogenation.
The role of the catalyst (Ni/Pd) is to provide a surface for the reaction to occur and to speed up the reaction without being consumed.
Concept Map
Carbon and its Compounds connects to →
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